Hosts went wild about Olivia Wilde in Marchesa. Talk about a fairy tale princess :)

Winning the Best Dressed nod from E!'s Fashion Police, Angelina Jolie represented well in Atelier Versace.

It was a fashion toss up for recently divorced Scarlett Johansson in who sported an Elie Saab gown and Bride of Frankenstein 'do.

Tiny and mighty, here is Eva Longoria in a form fitting Zac Posen, and I have to admit, this has "Eat your heart out, Tony Parker" written all over it.

Anne Hathaway dressed in full on Dynasty-inspired fashion with Armani Prive also received several Best Dressed nods!

Love it or hate it, here is Jennifer Lopez in a Zuhair Murad gown in white.

Who said redheads can't wear pink? Here's Julianne Moore sporting a hot pink gown, asymmetrical gown by Lanvin.

While I normally love everything about Halle and her berries, I can't say I'm nuts about this black Nina Ricci gown.

Both boo's and applause followed Lea Michele in her ultra fabric, pink Oscar de le Renta.

While Sandra Bullock's dress was mostly considered a miss, it was her hair that really had fans saying, "huh?"

Legendary risk taker Helena Bonham Carter really went all out in Vivienne Westwood and mismatched shoes ensemble... leaving me wonder, where were her friends to help!?

The always timeless and recently wed, Carrie Underwood, looked stunning in her champagne colored Badgley Mischka gown.

Also representing the nude color pallet - as well as a disco daisy pattern - Michelle Williams walked the red carpet in Valentino. And while I love Michelle and Valentino, I can't say I'm feeling this look.

Well, there goes the notion that super models can wear anything. Heidi Klum was looking a hot mess in this psychedelic Marc Jacobs getup.

Also recently newlywed, Megan Fox, played it safe in this blush colored Armani Prive gown, but I wouldn't mind to take home those shoes!

J. Love, is that you under there? Normally one of Hollywood's best bodies, Jennifer Love Hewitt seemed a bit drowned by her Romona Keveza gown.

Also rocking a Romona Keveza gown, Julia Stiles walked the red carpet in fierce, one-shouldered fashion.

Easy "A's" Emma Stone was almost unrecognizable in her skin toned Calvin Klein dress and recently bleached tresses, but I got to admit, I still kind of liked it :)

Not only did she look "oh so" in love with cancer surviving hubby, Michael Douglas, but Catherine Zeta-Jones was a knockout in this whimsical, jewel toned Monique Lhuillier number. Love it and love her!

Considered one of hot young Hollywood's royalty, I have to wonder what Leighton Meester was thinking wearing this dowdy, Burberry Prorsum design? She's much too cute to be so covered!

It was all about setting the red carpet on fire when Mad Men bombshell, Christina Hendricks entered wearing this Romona Keveza one shoulder gown. And while I love her and the dress, there's something a little too much (and too red) about it altogether.

Sporting the same jewel tone as Angelina and Catherine Zeta, Mila Kunis walked the red carpet in a form fitting Vera Wang.

January Jones let everyone know why she makes the "men mad" in this contemporary cut out gown by Versace.

Amy Adams went asymmetrical in her navy blue, frock top gown by Marchesa.

The curvaceous Sofia Vergara had jaws dropping in the corseted, two tone gown by Vera Wang, and while the reviews were mixed, there's no denying this bombshell's beauty!